秦正波

时间:2022-09-24    

秦正波,男,1983年,安徽无为人,博士,副教授,博士生导师。

通讯地址:安徽省芜湖市九华南路189号,

bat365在线中国官网登录入口。

邮编:241002

电子信箱:wave0403@163.com

教育经历:

2001/09-2005/07安徽师范大学,物理学(师范),本科

2005/09-2008/07安徽师范大学,原子与分子物理,硕士

2010/09-2014/01中国科学院大连化学物理研究所, 物理化学, 博士

工作经历:

2017.07-至今,安徽师范大学,bat365在线中国官网登录入口,副教授

2014.07-2017.06,安徽师范大学,bat365在线中国官网登录入口,讲师

2015.10-2016.09,美国西北太平洋国家实验室,环境分子科学实验室,访问学者

2008.07-2010.09,中国科学院大连化学物理研究所,分子反应动力学国家重点实验室,研究助理

研究领域:

1.大气环境相关的自由基的电子谱学实验和理论研究;

2.过渡金属配合物的化学键和结构性能研究;

3.离子-溶剂和溶剂-溶剂氢键相互作用机理的实验和理论研究;

4.生物相关分子抗氧化机理研究及健康相关检测应用;

5.高分辨慢电子速度成像谱仪和高分辨飞行时间质谱的开发及应用;

讲授课程:

1.线性代数

2.大学物理实验I,II,III

3.光信息专业实验

科研项目:

1.中国科学院高功率激光物理重点实验室开放课题项目(SGKF202106):激光诱导超声解析机理及质谱联用技术应用研究,2021.1-2022.12,主持;

2.国家自然科学基金面上项目(21873003):慢电子速度成像研究半胱氨酸类抗氧剂分子氧化反应的微观机制,2019.1-2022.12,主持;

3.国家自然科学基金青年项目(21503003):Criegee反应中瞬态中间体的慢电子速度成像研究,2016.1-2018.12,主持;

4.国家自然科学基金委员会-广东省政府联合基金(第二期)超级计算科学应用研究专项(培育基金U1501501):广州“天河二号”超级计算机应用专项,2016-2017,主持;

5.安徽省自然科学基金(1608085QA10):含硫瞬态自由基的慢电子速度影像研究,2016.1-2017.12,主持;

6.安徽省高等学校自然科学研究重点项目(KJ2015A032):慢电子速度成像研究萜烯类化合物基态及激发态结构特征,2016.1-2017.12,主持;

7.固体表面物理化学国家重点实验室开放基金(201708):硫醇保护贵金属(金银铜)纳米团簇自组装过程的气相合成、电子谱学表征及光物化性质理论研究,2018.1-2019.12,主持;

8.安徽省高校协同创新项目(GXXT-2020-004):聚变等离子体脱靶的关键物理过程研究,2021.01-2022.12,参与;

研究论文:

https://www.researchgate.net/profile/Zhengbo-Qin/research

http://www.letpub.com.cn/index.php?page=journalapp(IF)

50.Zhengbo Qin*,Qiaolin Wang, Lihe Xu, Wenjing Lv, and Xianfeng Zheng, "Hydrogen bonds in mixed-solvent Au-(CH3OH)(H2O) complex: A joint experimental and theoretical study",Chemical Physics Letters,2022,803,139854. (DOI: 10.1016/j.cplett.2022.139854;ISSN:0009-2614;)

49.Jingxiong Yu, Fanggang Liu, Zefeng Deng, Zaifa Shi, Jiangle Zhang, Qiaolin Wang, Jing Yang, Haoquan Hu,Zhengbo Qin*,and Zichao Tang* "Insights into a Low-Rank Naomaohu Coal Structural Information by Multistage Fractions Coupled with LIAD-VUVPI-TOFMS",ACS Omega,2022, 7, 6935−6943. (DOI: 10.1021/acsomega.1c06619; ISSN:2470-1343; 2022.2.17)

48.Zhenhang Jin, Jiangle Zhang, Shan-jun Chen, Yan Chen, Weibing Zhang, Zaifa Shi, Jingxiong Yu, Song Li, Zichao Tang,Zhengbo Qin, "Probing the geometric and electronic structures of the lanthanide oxide HoOn-1/0 (n = 1-3) clusters",Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy,2021, 248,119287.(DOI: 10.1016/j.saa.2020.119287; ISSN:1386-1425; 2022.3.5).

47.Wei Guo*, Xianfeng Zheng,*,Zhengbo Qin,Qijia Guo, Lei Liu, Hydrogen Production from Ethanol Reforming by Microwave Discharge Using Air as Working Gas,ACS Omega,2021, 6, 33533−33541.(DOI: 10.1016/j.saa.2020.119287; ISSN:2470-1343;2021.11.30).

46.Jiangle Zhang, Shanjun Chen, Jingxiong Yu, Zefeng Deng,Zhengbo Qin*,Xingtai Qiu, Yihuang Jiang, Chengxiang Jiao, and Zichao Tang* "Deciphering the Superatomic Behavior of Group V Metal Monoxides",Journal of Physical Chemistry Letters,2021, 12, 7636−7640. (1948-7185; DOI: 10.1021/acs.jpclett.1c01971;ISSN:1948-7185; 2021.8.5)

45.Jingxiong Yu, Yuwan Chen, Jiangle Zhang, Shanjun Chen, Qiaolin Wang,Zhengbo Qin*, and Zichao Tang* “Development of a miniature time of flight mass spectrometer coupled with an improved substrate-enhanced laser-induced acoustic desorption source (SE-LIAD/TOF-MS)”,Analyst,2021, 146, 4365-4373. (0003-2654;DOI: 10.1039/D1AN00696G;ISSN:0003-2654; 2021.6.3)

44.Jiangle Zhang, Shanjun Chen, Yihuang Jiang, Chen Wang,Zhengbo Qin*, Xingtai Qiu, Jingxiong Yu, Yuwan Chen and Zichao Tang*“The photoelectron-imaging spectroscopic study and chemical bonding analysis of VO2-, NbO2-and TaO2-”,RSC Advances,2020, 10, 41612-41617.(DOI: 10.1039/D0RA07583C;ISSN:2046-2069;2020.11.13

43.Shanjun Chen,Jiangle Zhang,Zhenhang Jin, Xingtai Qiu,Zhengbo Qin*,Zichao Tang*, and Lansun Zheng,“Aromaticity Criterion Is Not the Only Factor to Decide the Ring Stability of Boron Oxide Families: c‑M2O2−/0Clusters (M = B, Al, Ga,and In)”,InorganicChemistry,2020,59, 16944−16951.(DOI:10.1021/acs.inorgchem.0c02028;ISSN: 0020-1669 ;2020.11.2)

42.Zhengbo Qin*,Gao-Lei Hou, Zheng Yang, Marat Valiev*and Xue-Bin Wang*, “Distonic radical anion species in cysteine oxidation processes”,Physical Chemistry Chemical Physics,2020,22, 17554-17558.(DOI: 10.1039/D0CP02165B; ISBN: 1463-9076;2020.7.10)

41.Jia-nan Fan,Ting-ting Cui,Zhengbo Qin*,Xian-feng Zheng*,Zhi-feng Cui, “Experimental and Theoretical Study on p-Chlorofluorobenzene in the S0, S1and D0States”,Chinese Journal of Chemical Physics,2020,33, 401.(DOI: 10.1063/1674-0068/cjcp2001005;ISSN: 1674-0068;2020.2.19)

40.Zhengbo Qin*, Jiangle Zhang, Chen Wang, Lin Wang, and Zichao Tang*, “Does gold behaves as hydrogen? A joint theoretical and experimental study”,Nanoscale Advances,2020, 2, 844-850.(DOI: 10.1039/C9NA00780F;ISSN: 2516-0230;2020.1.6)

39.Zhiling Liu, Lina Hou, Ya Li, Gang Li,Zhengbo Qin,Hai-Shun Wu, Jianfeng Jia, Hua Xie, and Zichao Tang, "Thermodynamics and Kinetics of Gas-Phase CO Oxidation on the Scandium Monoxide Carbonyl Complexes",The Journal of Physical Chemistry A,2020, 124, 5, 924–931,(DOI: 10.1021/acs.jpca.9b10659;ISSN: 1089-5639;2020.1.13)

38.Shifeng Qian, Xiaowei Sheng*, Xian Xu, Yuxiang Wu,Ning Lu,Zhengbo Qin, Jian Wang, Caixia Zhang, Eryin Feng, Wuying Huang and Yong Zhou,“Penta-MX2 (M = Ni, Pd and Pt; X = P and As) monolayers: direct band-gap semiconductors with high carrier mobility”Journal of Materials Chemistry C,2019, 7, 3569.(DOI: 10.1039/C8TC06030D;ISSN: 2050-7526;2019.2.21)

37.Jiangle Zhang,Zhengbo Qin*,Chengxiang Jiao, and Zichao Tang*, “Photoelectron imaging spectroscopic study and chemical-bonding analysis of AgOH and AgSH anions”,Journal of Quantitative Spectroscopy & Radiative Transfer,2019,233, 52-56.(DOI: 10.1016/j.jqsrt.2019.05.015;ISSN: 0022-4073;2019.5.14)

36.Zhengbo Qin*, Lin Wang, Ran Cong, Chengxiang Jiao, Xianfeng Zheng, Zhifeng Cui, and Zichao Tang*, “Spectroscopic identification of the low-lying electronic states of S2molecule”,Journal of Chemical Physics,2019, 150, 044302.(DOI: 10.1063/1.5080458;ISSN: 0021-9606;2019.1.22)

35.Chengxiang Jiao,Zhengbo Qin*,Ran Cong, Xianfeng Zheng, Zhifeng Cui, Hua Xie*, and Zichao Tang*, “A comparative study on the bond features in CO, CS, and PbS”,Journal of Chemical Physics,2018, 149, 224302.(DOI: 10.1063/1.5067006;ISSN: 0021-9606;2018.12.11)

34.Zhengbo Qin*,Naiyu Ma, Yangdi Ren, Xianfeng Zheng*, Guanxin Yao, Xianyi Zhang and Zhifeng Cui, “Analysis of the S1←S0and D0←S1spectra in m-bromofluorobenzene via resonance-enhanced multiphoton ionization and slow electron velocity-map imaging spectroscopy”Journal of Quantitative Spectroscopy & Radiative Transfer,2019,224, 107-113.(DOI: 10.1016/j.jqsrt.2018.11.008;ISSN: 0022-4073;2018.11.7)

33.Yangdi Ren,Zhengbo Qin*,Hui Wang, Xianfeng Zheng*, and Zhifeng Cui, “An approach for improving signal-to-noise ratio in photoelectron velocity map imaging experiments”Journal of Electron Spectroscopy and Related Phenomena,2018,222, 5-9.(DOI: 10.1016/j.elspec.2017.11.001;ISSN: 0368-2048;2017.11.8)

32.Jonas Warneke, Gao-Lei Hou, Edoardo Aprà, Carsten Jenne, Zheng Yang,Zhengbo Qin, Karol Kowalski, Xue-Bin Wang*and Sotiris S. Xantheas*, “Electronic Structure and Stability of [B12X12]2-(X=F−At): A Combined Photoelectron Spectroscopic and Theoretical Study”,Journal of the American Chemical Society,2017,139,14749–14756(DOI: 10.1021/jacs.7b08598;ISSN: 0002-7863;2017.9.21)

31.Zhengbo Qin*,Hui Wang, Yangdi Ren, Xianfeng Zheng, and Zhifeng Cui, and Zichao Tang*, “Electron velocity map imaging and theoretical study on CuXH (X=O and S) anions”Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,2017, 188, 85-89.(DOI: 10.1016/j.saa.2017.06.039;ISSN: 1386-1425;2017.7.4)

30.Zehua Qu,Zhengbo Qin*, Hui Wang, Yangdi Ren, Xianfeng Zheng*, GuanxinYao, Xianyi Zhang, and Zhifeng Cui, "Spectroscopic characterization on the neutral excited state and cationic ground state of styrene"International Journal of Mass Spectrometry,2017, 414,56-64(DOI: 10.1016/j.ijms.2017.01.008;ISSN: 1387-3806;2017.1.20)

29.Zehua Qu,Zhengbo Qin*, Xianfeng Zheng*, Hui Wang, Guanxin Yao, Xianyi Zhang, Zhifeng Cui, “Slow-electron velocity-map imaging study of aniline via resonance-enhanced two-photon ionization method”Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,2017, 173, 432-438.(DOI:10.1016/j.saa.2016.09.046;ISSN: 1386-1425;2016.2.28)

28.Zhengbo Qin, Gaolei Hou, Zheng Yang Marat Valiev*, Xuebin Wang*, “Negative ion photoelectron spectra of ISO3, IS2O3, and IS2O4intermediates formed in interfacial reactions of ozone and iodide/sulfite aqueous microdroplets”Journal of Chemical Physics,2016, 145 (21), 214310.( DOI: 10.1063/1.4969076;ISSN: 0021-9606;2016.12.6)

27.Zehua Qu, Chunsheng Li,Zhengbo Qin*, XianfengZheng*, Guanxin Yao, Xianyi Zhang, Zhifeng Cui “The design of double electronstatic-lens optics for REMPI and photoelectron imaging experiments”Review of Scientific Instruments,2015, 86, 063106.(DOI: 10.1063/1.4922521;ISSN: 0034-6748;2015.6.16)

26.Zhengbo Qin*,Chunsheng Li, Zehua Qu, Zhifeng Cui, Xianfeng Zheng, Zichao Tang*, “Note: A simple method to suppress the artificial noise in velocity-map imaging spectroscopy”Review of Scientific Instruments,2015, 86, 046102. (DOI:10.1063/1.4916716;ISSN: 0034-6748;2015.4.1)

25.Zhiling Liu, Hua Xie,Zhengbo Qin, Hongjun Fan*, Zichao Tang*, “Structural Evolution of Homoleptic Heterodinuclear Copper–Nickel Carbonyl Anions Revealed Using Photoelectron Velocity-Map Imaging”Inorganic Chemistry,2014, 53, 10909–10916(DOI: 10.1021/ic501070u;ISSN: 0020-1669;2014.10.3)

24.Zhengbo Qin,Ran Cong, Hua Xie, Zhiling Liu, Xia Wu, Zichao Tang*, Hongjun Fan*, and Ling Jiang*. “Photoelectron Imaging and Theoretical Study on Nascent Hydrogen Bond Network in Microsolvated Clusters of Au(CH3OH)n(n= 1-5)”,The Journal of Physics Chemical A,2014,118 (19), 3402-3409. (DOI: 10.1021/jp411411j;ISSN: 1089-5639;2014.4.28)

23.Zhengbo Qin, Ran Cong, Xia Wu, Zhiling Liu, Hua Xie, Zichao Tang*, Ling Jiang*, and Hongjun Fan*.“Photoelectron imaging and theoretical study on the structure and chemical binding of the mixed-ligand M(I) complexes, [HMSH]- (M = Cu, Ag, and Au)”,Journal of Chemical Physics,2014,140, 114307. (DOI: 10.1063/1.4868553;ISSN: 0021-9606;2014.3.19)

22.Zhengbo Qin, Ran Cong, Zhiling Liu, Hua Xie, Zichao Tang*, and Hongjun Fan*.“An investigation into low-lying electronic states of HCS2via threshold photoelectron imaging”,Journal of Chemical Physics,2014,140, 214318.(DOI: 10.1063/1.4879808;ISSN: 0021-9606;2014.6.6)

21.Zhengbo Qin*, Ran Cong,Zhiling Liu, Hua Xie, Zichao Tang*.“Low-energy photoelectron imaging of HS2anion”Journal of Chemical Physics,2014,141,204312.(DOI: 10.1063/1.4901978;ISSN: 0021-9606;2014.11.26)

20.Zhiling Liu, Hua Xie, Quanjiang Li,Zhengbo Qin, Ran Cong, Xia Wu, Zichao Tang* and Hongjun Fan*, "On the photoelectron velocity-map imaging of lutetium monoxide anion LuO",Journal of Chemical Physics,2014,140, 034312(DOI: 10.1063/1.4862142;ISSN: 0021-9606;2014.1.17)

19.Hua Xie, Jie Wang,Zhengbo Qin,Lei Shi, Zichao Tang*, and Xiaopeng Xing*, "Octacoordinate Metal Carbonyls of Lanthanum and Cerium: Experimental Observation and Theoretical Calculation",The Journal of Physical Chemistry A,2014,118, 40, 9380–9385.(DOI: 10.1021/jp504079k;ISSN: 1089-5639;2014.9.9)

18.Zhiling Liu, Zhengbo Qin, Xia Wu, Hua Xie, Ran Cong, and Zichao Tang*,“Vibrationally Resolved Photoelectron Imaging of Au3H”,Journal of Physical Chemistry A,2014,118, 1031−1037.(DOI: 10.1021/jp411639r;ISSN: 1089-5639;2014.1.24)

17.Zhengbo Qin*Xia Wu, Zichao Tang*. “Note: A novel dual-channel time-of-flight mass spectrometer for photoelectron imaging spectroscopy”,Review of Scientific Instruments2013, 84, 066108.(DOI: 10.1063/1.4811739;ISSN: 0034-6748;2013.6.7)

16.Zhengbo Qin, Ran Cong, Xia Wu, Zhiling Liu, Hua Xie, Zichao Tang*, Ling Jiang*, and Hongjun Fan*.“Photoelectron velocity-map imaging spectroscopic and theoretical study on the reactivity of the gold atom toward CH3SH, CH3OH, and H2O”,Journal of Chemical Physics,2013, 139, 034315.(DOI: 10.1063/1.4813631;ISSN: 0021-9606;2013.7.18)

15.Zhengbo Qin,Xia Wu, Zichao Tang*. “Design near-threshold photoelectron imaging spectrometer based on UV laser induced photoelectron emission anion source”,Chinese Journal of Chemical Physics2013, 26, 774. (DOI: 10.1063/1674-0068/26/06/774-779;ISSN: 1674-0068;2013.10.29)

14.Hua Xie, Xiaoyi Li, Lijuan Zhao, Zhiling Liu,Zhengbo Qin,Xia Wu, Zichao Tang* and Xiaopeng Xing*,“Vibrationally Resolved Photoelectron Imaging of Cu2Hand AgCuHand Theoretical Calculations”,Journal of Physical Chemistry A,2013,117, 1706−1711(DOI: 10.1021/jp310809k;ISSN: 1089-5639;2013.2.6)

13.Zhiling Liu,Zhengbo Qin, Hua Xie,Ran Cong,Xia Wu,Zichao Tang*. “Structure of Au40/-1in the Gas Phase: A Joint Geometry Relaxedab initioCalculations and Vibrationally Resolved Photoelectron Imaging Investigation”.Journal of Chemical Physics,2013,139, 094306.(DOI: 10.1063/1.4819789;ISSN:0021-9606;2013.9.4)

12.Hua Xie, Xiaopeng Xing, Zhiling Liu, Ran Cong,Zhengbo Qin, Xia Wu, Zichao Tang*and Hongjun Fan*. “Photoelectron imaging and theoretical calculations of gold-silver hydrides: Comparing the characteristics of Au, Ag and H in small clusters”Physical Chemistry Chemical Physics,2012,14, 11666-11672.(DOI: 10.1039/c2cp41164d;ISSN: 1463-9076;2012.7.6)

11.Hua Xie, Xiaopeng Xing, Zhiling Liu, Ran Cong,Zhengbo Qin, Xia Wu, Zichao Tang*, and Hongjun Fan*, “Probing the structural and electronic properties of AgnH(n = 1–3) using photoelectron imaging and theoretical calculations”Journal of Chemical Physics,2012,136, 184312.(DOI:10.1063/1.4713938;ISSN:0021-9606;2012.5.11)

10.Hua Xie,Zhengbo Qin, Xia Wu, Zichao Tang*and Ling Jiang*. “Photoelectron Velocity-Map Imaging Signature of Structural Evolution of Silver-Doped Lead Zintl Anions”Journal of Chemical Physics,2012,137, 064318.(DOI: 10.1063/1.4745000;ISSN: 0021-9606;2012.8.13)

9.Zhiling Liu,Hua Xie,Zhengbo Qin,Ran Cong,Xia Wu,Zichao Tang*,Xin Lu*andJian He. “Vibrationally Resolved Photoelectron Imaging of Platinum Carbonyl Anion Pt(CO)n-(n=1-3): Experiment and Theory”Journal of Chemical Physics,2012,137, 204302.(DOI: 10.1063/1.4768004;ISSN:0021-9606;2012.11.27)

8.Hua Xie,Xiaoyi Li,Lijuan Zhao,Zhengbo Qin,Xia Wu, Zichao Tang,*, Xiaopeng Xing*, "Photoelectron Imaging and Theoretical Calculations of Bimetallic Clusters: AgCu-, AgCu2-, and Ag2Cu-",The Journal of Physical Chemistry A,2012,116, 10365–10370.(DOI: 10.1021/jp307478x;ISSN: 1089-5639;2012.10.1)

7.Xinghua Liang#, Xia Wu#, Ting Dong#,Zhengbo Qin, Kai Tan, Xin Lu*, and Zichao Tang*. “The Dinitrogen-Ligated Triaurum Cation, Aurodiazenylium, Auronitrenium, Auroammonia, and Auroammonium” .Angewandte Chemie International Edition,2011,50(9), 2166-2170.(DOI: 10.1002/anie.201007332;ISSN: 1433-7851;2011.2.1)

6.Xia Wu, Hua Xie,Zhengbo Qin,Kai Tan, Zichao Tang*, and Xin Lu*, "Photoelectron Imaging and Theoretical Studies of Silver Monohalides AgX- (X = Cl, Br, I) and AuCl-",The Journal of Physical Chemistry A,2011,115, 6321–6326.(DOI: 10.1021/jp1100686;ISSN:1089-5639;2011.5.26)

5.Xia Wu,Zhengbo Qin, Hua Xie, Ran Cong, Xiaohu Wu, Zichao Tang* and Hongjun Fan*. “Vibrationally resolved photoelectron imaging of gold hydride cluster anions: AuH-and Au2H-Journal of Chemical Physics,2010,133, 044303.(DOI: 10.1063/1.3456373;ISSN: 0021-9606;2010.7.23)

4.Xia Wu, Zhengbo Qin, Hua Xie, Xiaohu Wu, Ran Cong, and Zichao Tang*, "Collinear Velocity-map Photoelectron Imaging Spectrometer for Cluster Anions",Chinese Journal of Chemical Physics,2010,23, 373.(DOI:10.1088/1674-0068/23/04/373-380;ISSN: 1674-0068;2010.1.1)

3.王辉,曲泽华,秦正波*,郑贤锋*,姚关心,张先燚,崔执凤,”基于共振增强多光子电离技术的慢电子速度影像应用”,原子与分子物理学报2016, 33(6)957-962

2.秦正波,“一种改进惠斯通电桥和交流电桥实验教学效果的简单方法”,大学物理实验202235,60-62

1.秦正波,汪桥林,王林,王晨,杨新艳,郑贤锋,崔执凤,“食品中多环芳烃检测方法的研究进展”,安徽师范大学学报(自然科学版)202245,29-34。


专利:

[1]一种薄型真空密封连接阀装置,秦正波,吴侠,唐紫超,曲泽华,实用新型专利,申请号:201220079051.4,授权号:ZL201220079051.4

[2]一种同向双通道飞行时间质谱仪,秦正波,唐紫超,张世宇,发明专利,申请号:201310016591.7,授权号:ZL201310016591.7

[3]一种可调距式充气激光真空紫外灯装置,汪桥林,秦正波,许立河,实用新型专利,授权号:ZL202123209598.X

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